منابع مشابه
The Basics of Karl Fischer Titration
From the reaction mechanism, it's evident that the reagent used for the titration needs to contain the following: Alcohol methanol was used originally, but in different variations of the reagent can be replaced by ethyl carbitol, methoxypropanol, ethanol, etc. Sulfur dioxide Iodine Base pyridine was used initially, but has since been replaced by imidazole, which assures a higher rate of reactio...
متن کاملMeasuring Moisture in Lubricants with FTIR: An Alternative to Karl Fischer Titration
A rapid and accurate primary Fourier transform infrared (FTIR) method for the determination of moisture in mineral and ester based lubricants has been developed based on the extraction of moisture into dry acetonitrile. A Continuous Oil Analyzer and Treatment (COAT) FTIR system was programmed to allow the automated analysis of acetonitrile extracts, and the methodology was validated by analyzin...
متن کاملSimple Modification of Karl-Fischer Titration Method for Determination of Water Content in Colored Samples
The most commonly used technique for water content determination is Karl-Fischer titration with electrometric detection, requiring specialized equipment. When appropriate equipment is not available, the method can be performed through visual detection of a titration endpoint, which does not enable an analysis of colored samples. Here, we developed a method with spectrophotometric detection of a...
متن کاملSome remarks on Mechanism and kinetics of the coulometric variant of the Karl-Fischer titration reaction
• A submitted manuscript is the author's version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version ...
متن کاملMechanism and Reaction Rate of the Karl-fischer Titration Reaction Part I. Potentiometric Measurements
The react ion rate of the cou lomet r ic variant of the Karl-Fischer t i t ra t ion reac t ion (in which electrolyt ical ly generated t r i iodide is used as ox idan t instead of iodine) has been measured in methanol . The react ion is first order in water , sulfur d ioxide and t r i iodide, respectively. For pH < 5 the react ion rate cons tan t decreases logari thmical ly wi th decreasing pH. ...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1965
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.14.871